HW 5 Ketones Aldehydes_page_1
CHEM 3332 Honors Homework for Ketones and Aldehydes 1. Draw a structure for the following: A. 4-tert-butylcyclohexanone D. 2-pentanone B.…
HW 5 Ketones Aldehydes_page_2
{e) 2 equiv HSEt ——_> cat H+ F. Oo Zn(Hg) HCI G. {e) H NaCN —_ > HCI (2 equiv) H. B P(OEt); 1) FBUOK THE t-BuOK, THF r Ns SE cael 2) 2PhCHO…
HW 5 Ketones Aldehydes_page_3
or AU 3. Give reagents to perform the following transformations. A. 1) PhP 3) heat Carvone (spearmint oil) 2) NaOt-Bu —.— ew > > —. oer > .…
HW 5 Ketones Aldehydes_page_4
BrH,C CO2H H,C OH
HW 5 Ketones Aldehydes_page_5
CN Cr > (eo) N H Q. {e) R. “Sou > oun S. CHO CO,Me ZA~co.Me ——— > CHO T. H OH yo fe) [e) U. ioe . ne tl Ge V. Co 4. Write a full mechanism…
HW 5 Ketones Aldehydes_page_6
6. What is wrong with the following? A. —_™~ mab ——_ > {e) OH B. —y" wast —______ > oT C. 0 > ae ~ y Nar {e) fo) D. LiAIH, > {e) E. — OT 7…
HW 5 Ketones Aldehydes_page_7
7.Predict the product for each of these reactions. For either A or B, draw the full mechanism for the transformation. A H,0* fe) B H3,0+ 8.…
HW 5 Ketones Aldehydes_page_8
9. Provide the structure for the following: A. C10Hi00 shift in ppm integration multiplicity 8.01 7.46 7.33 id id 7.21 2.93 2.63 d d d d t…
HW 5 Ketones Aldehydes_page_9
B. CgHi0O0 shift in | integration | multiplicity ppm A_| 6.09 1 s B | 2.16 3 s Cc | 2.14 3 s D 1.89 3 s T T T T T T T T T T T T 11 109 8 7…